A comprehensive set of practice problems on the reactions of alcohols including substitution, elimination, oxidation, as well as multistep synthesis through the formation of alkenes and subsequent addition reactions.
Provide reagents to achieve the following transformations in one-pot synthesis (use only one reagent):
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Predict the product(s) that are formed after each step for reactions A-G. In each case, consider formation of any chiral center(s) and draw all expected stereoisomers.
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The full Video solution to the problems:
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Complete the following synthesis by adding the missing reagent(s) for each step and the structures for compound A and B:
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Complete the following synthesis by adding the missing reagent(s) for each step and the structures for compound A and B:
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Complete the following synthesis by adding the missing reagent(s) for each step and the structures for compound A and B:
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Complete the following synthesis by adding the missing reagent(s) for each step and the structures for compound A and B:
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Complete the following synthesis by adding the missing reagent(s) for each step and the structures for compound A and B:
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Predict the major product when each of the following alcohols is treated with H2SO4:
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Draw a suitable mechanism for each transformation:
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Predict the major organic product when the following alcohol is treated with each oxidizing agent:
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Predict the major organic product for each of the following alcohol oxidation reactions:
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A) Determine the missing intermediates and reagents in the following synthesis.
As you may remember from the reactions of alkenes, bromination of a double bond proceeds via formation of a cyclic bromonium ion intermediate.
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